ASTM D4629 - Trace Nitrogen in Liquid Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection

Significance and Use

4.1 Some process catalysts used in petroleum and chemical refining may be poisoned when even trace amounts of nitrog-enous materials are contained in the feedstocks. This test method can be used to determine bound nitrogen in process feeds and may also be used to control nitrogen compounds in finished products.

Scope

1.1 This test method covers the determination of the trace total nitrogen naturally found in liquid hydrocarbons boiling in the range from approximately 50 °C to 400 °C, with viscosities between approximately 0.2 cSt and 10 cSt (mm2/s) at room temperature. This test method is applicable to naphthas, distillates, and oils containing 0.3 mg ⁄kg to 100 mg ⁄kg total nitrogen. For liquid hydrocarbons containing more than 100 mg ⁄kg total nitrogen, Test Method D5762 can be more appropriate. This test method has been successfully applied, during interlaboratory studies, to sample types outside the range of the scope by dilution of the sample in an appropriate solvent to bring the total nitrogen concentration and viscosity to within the range covered by the test method. However, it is the responsibility of the analyst to verify the solubility of the sample in the solvent and that direct introduction of the diluted sample by syringe into the furnace does not cause low results due to pyrolysis of the sample or solvent in the syringe needle.

Extracted, with permission, from ASTM D4629-17 - Trace Nitrogen in Liquid Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection, copyright ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428. A copy of the complete standard may be purchased from ASTM International, astm.org